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January 06, 2008

バイオエタノールとETBE

宮古島のバイペエタノール構想の頓挫は石油業界との見解の不一致のようだった。
次のニュース記事に詳しかった。
http://kyushu.yomiuri.co.jp/news/ne_08010551.htm

宮古島は、エタノールの原料になるサトウキビの生産が盛んで、国の補助金などで島内2か所の製糖工場にエタノール製造設備を併設し、年間約750キロ・リットルを生産する計画だった。構想は島内の産業振興にも役立つと期待されていた。
 しかし、島内で16か所の系列スタンドを抱える新日本石油など元売り大手が協力を拒み、全量切り替えの構想は困難になった。
 元売りの業界団体である石油連盟(会長=渡文明・新日石会長)はE3とは別方式の、エタノールを化学反応させた「ETBE」と呼ばれる燃料添加剤とガソリンの混合燃料の普及を進めている。「E3は水が入るとエタノールが溶けて分離し、品質維持が難しい」(渡会長)ことなどが協力を拒否した理由だ。

 ETBEとは、エチルターシャリーブチルエーテルで、オクタン価を高める為の添加剤として用いられるらしい。
 ETBEについては、次のブログに詳しい。2005年3月の記事である。
http://tftf-sawaki.cocolog-nifty.com/blog/2005/03/etbe.html

ガソリンにバイオエタノールを混合した「E3」とか「E10」というのは聞いたことがあるのだが、これについては環境省が推進している反面で、石油業界から品質等を理由に強い反対がある他、ガソリン以上にNOx発生が増えるという懸念もあるらしい。
で、最近注目を浴び始めているのがETBEらしい。これを7%程度添加すると、E3と同等のCO2削減効果が期待され、石油業界も導入には前向きらしい。

というように、バイオエタノールより、添加剤のETBEの方が環境に優しいという意見のようだ。
 次のような記事もあった。2007年3月の記事だ。
http://techtech.jp/jdl/weblog/blog/10/13968
 
石油業界のバイオ燃料組合、ガソリン添加剤・ETBEを来月輸入開始
 [ 2007年03月07日 10時00分 ]
 石油業界が設立したバイオマス燃料供給有限責任事業組合(東京都港区)は、バイオエタノールに添加剤を加えたエチル・ターシャリー・ブチル・エーテル(ETBE)を4月から輸入する。
このため受け入れ基地となる新日本石油根岸製油所(横浜市磯子区)に受け入れ桟橋やパイプラインを設置する。さらに同社は休止中のメチルターシャリー・ブチル・エーテル(MTBE)のプラントに数十億円を投じて今秋からETBE用に転換。プラント改造で先陣を切る。
 石油業界は京都議定書で定められた二酸化炭素(CO2)の削減目標を達成するため、2010年には36万キロリットルのバイオエタノールを導入。すべてをエタノール3%とイソブチレンを混ぜたETBEでの製品化を目指している。このためバイオエタノール、ETBEの輸入と国内各社への輸送を担当する有限責任事業組合を設立。運営を始めた。5月からまず首都圏の50の給油所(SS)で実証を行うため、新日石の根岸製油所にフランスからETBEを輸入する。このため3月末までに流通実証事業として桟橋の改造やパイプラインを新設。貯蔵タンクは既設タンクをベースに、専用2基のタンクとETBEブレンド用のガソリンタンク1基(いずれも容量は1万8000キロリットル)に転用を図る。船は月1回のペースで6700キロリットルを運ぶ。このタンクから各社が直接、各地のSSにETBEを供給する。(日刊工業新聞)

一方、ETBEの危険性については、次のブログに詳しい。2007年5月の記事である。
ネットで関連記事は見つかられたが、結論を1つにまとめられない。

http://ameblo.jp/doe136/entry-10033231566.html

以前軽く触れましたが、ETBEはエタノール直接混合と比較し絶対優位であるかのような説明が石連からなされています。 また、同時に現時使用している国がドイツ・フランス・スペインなのでその有毒性など十分究明されていないがたぶん問題が無いのではないかと発言し、現在ちょっと後悔をしています。 何故なら、毒性・発がん性等、安易な解釈は許されるものではないからです。

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